Redistribution of reactive nitrogen in the Arctic lower stratosphere in the 1999/2000 winter

M. Koike (1) , Y. Kondo (2) , N. Takegawa (2) , Franck Lefèvre (3) , H. Ikeda (2) , H. Irie (4) , H. D. E. Hunton (5) , A. A. Viggiano (5) , T. M. Miller (5) , J. O. Ballenthin (5) , G. W. Sachse (6) , B. E. Anderson (6) , M. Avery (6) , Y. Masui (7)

1 Department of Earth and Planetary Sciences [Rehovot]
2 RCAST - Research Center for Advanced Science and Technology [Tokyo]
3 SA - Service d'aéronomie
4 NIES - National Institute for Environmental Studies
5 AFRL - Air Force Research Laboratory
6 LaRC - NASA Langley Research Center [Hampton]
7 Department of Earth and Planetary Science [Tokyo]

Total reactive nitrogen (NO_y) in the Arctic lower stratosphere was measured from the NASA DC-8 aircraft during the SAGE III Ozone Loss and Validation Experiment (SOLVE) in the winter of 1999/2000. NO_y-N₂O correlations obtained at altitudes of 10-12.5 km in December 1999 and January 2000 are comparable to the reported reference correlation established using the MkIV balloon measurements made during SOLVE prior to the onset of denitrification. Between late February and mid-March, NO_y values obtained from the DC-8 were systematically higher than those observed in December and January by up to 1 part per billion by volume, although a compact correlation between NO_y and N₂O was maintained. Greater increases in NO_y were generally observed in air masses with lower N₂O values. The daily minimum temperatures at 450-500 K potential temperature (∼20-22 km) in the Arctic fell below the ice saturation temperature between late December and mid-January. Correspondingly, intense denitrification and nitrified air masses were observed from the ER-2 at 17-21 km and below 18 km, respectively, in January and March. The increases in NO_y observed from the DC-8 in late February/March indicate that influence from nitrification extended as low as 10-12.5 km over a wide area by that time. We show in this paper that the vertical structure of the temperature field during the winter was a critical factor in determining the vertical extent of the NO_y redistribution. Results from the Reactive Processes Ruling the Ozone Budget in the Stratosphere (REPROBUS) three-dimensional chemistry transport model, which reproduced the observed general features only when the NO_y redistribution process is included, are also presented.

Keywords: Middle atmosphere-composition and chemistry; Middle atmosphere-constituent transport and chemistry; Arctic region; reactive nitrogen; NO<SUB>y</SUB>; Arctic; ozone; denitrification; nitrification

Domains: Sciences of the Universe [physics]

M. Koike, Y. Kondo, N. Takegawa, Franck Lefèvre, H. Ikeda, et al.. Redistribution of reactive nitrogen in the Arctic lower stratosphere in the 1999/2000 winter. Journal of Geophysical Research: Atmospheres, 2002, 107 (D20), pp.SOL 17-1-SOL 17-16. ⟨10.1029/2001JD001089⟩. ⟨hal-04110047⟩